When triggering “Clip to DEVONthink” using hotkey, the sorter does not gain the focus, and the ⌘ + S shortcut will not work. You have to click the sorter to gain focus first then press ⌘ + S to import the web page.
The whole point of hotkey is that you don’t have to move cursor around to get what you want. So I assume this will to be improved in future?