Is it possible to Export Files in Smart Rule?

undefined is actually not an error here but just the result of running the script. Since it does nothing …

As to your question: The function working on the current selection looks like the one below. It’s of course not very elegant to hard-wire the target folder, instead it could ask the user for it, at least in the stand-alone script.

(() => {
  const externalFolder = "Posix/Path/To/Folder";
  const app = Application("DEVONthink 3");
  app.selectedRecords().forEach(r => app.export({record: r}, {to: externalFolder}));
})()

There’s also this

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