New to DEVONthink: Seeking Advice on Sync & Storage

For years I synced several macs and iPads (with DTG 3) using WebDav (on a Synology NAS) without a problem. After installing DTG 4 on the ipads I can no longer setup a working sync. I installed DTG 3 and 4 in parallel, and 3 works, 4 doesnt. Is there an explanation?